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481.
Mohd Anis G. G. Muley M. D. Shirsat S. S. Hussaini 《Crystal Research and Technology》2015,50(5):372-378
Optically transparent formic acid (FA) doped potassium dihydrogen phosphate (KDP) crystal of dimension 21×15×9 mm3 has been grown by slow evaporation solution technique (SEST). The X‐ray diffraction (XRD) technique was used to confirm the cell parameters and the shifts in peak positions of identified reflecting planes. The incorporation of FA in KDP has been qualitatively analyzed by fourier transform infrared analysis. The UV‐visible absorption spectrum of crystals has been recorded in the range of 200 to 900 nm and the doped KDP crystal is found to have improved optical parameters than pure KDP. The color centered photoluminescence emission spectrum of grown crystal has been illustrated in visible region. The mechanical behavior of pure and doped KDP crystal has been investigated using the Vicker's microhardness analyzer and hardness parameters have been calculated. The effect of FA on thermal stability of KDP crystal was examined by means of thermogravimetric and differential thermal analysis. The temperature dependent dielectric behavior of crystals was studied. 相似文献
482.
The main purpose of this paper is to study the connection sequence between two polynomial sets. We prove that any two equivalent polynomial sets can be connected with a Sheffer sequence. The principal result presents a unification of some useful known results. The inversion, addition and duplication sequences are considered as particular cases. Moreover, some examples are given. 相似文献
483.
Mohamed Kharroubi Hamza Assad Sebastien Balme Lakhdar Gacem Cherif Maghni 《Ionics》2016,22(12):2355-2361
A series of zinc phosphate glass doped with cobalt Na2Zn(1???x)CoxP2O7 (x = 0, 1, 2 and 5 mol%) was synthesized. These glasses were characterized by both infrared and large broadband dielectric spectroscopy. Infrared spectra indicate the increase of Zn/Co ratio creates defect in phosphate network due to the depolymeration of phosphate anions. The dc conductivity increases and activation energy decreases with the amount of cobalt ions in the glass network. The impedance measurements reveal that the total conductivity follows Jonscher’s power law. The dielectric constant and dielectric loss increased with the temperature and decreased with the frequency whatever the cobalt proportion. 相似文献
484.
Stirling A Hamza A Rokob TA Pápai I 《Chemical communications (Cambridge, England)》2008,(27):3148-3150
A computational approach reveals cooperative action of the preorganized acidic and basic centers of the frustrated P(t-Bu)(3)/B(C(6)F(5))(3) Lewis pair on olefinic bonds as the key to the observed regioselective addition reaction. 相似文献
485.
Two new phytochemical compounds, Tetranins A and B, 1-(3,5'-dihydroxy-4'-méthoxyphenyl)-2-phenylethanol 1 and 5,2'-dihydroxy-5'-methoxy-6,7-methylenedioxy-isoflavone 2, were isolated from the EtOAc extract of Salsola tetrandra roots. They exhibited a significant antioxidant effect in 1,1-diphenyl-2-picrylhydrazyl (DPPH) free radical and 2,2'-azinobis (3-ethylbenzothiazoline-6-sulphonic acid (ABTS) assays. Their structures were elucidated by extensive spectroscopic methods including 1-D-((1)H and (13)C) and 2-D-NMR experiments (CHcorr, HMBC, (1)H-(1)H COSY and NOESY) as well as high-resolution ES-MS and they were found to be quite active as antioxidants in the DPPH and ABTS assays. 相似文献
486.
The effect of calcination temperatures on dry reforming catalysts supported on high surface area alumina Ni/γ-Al2O3 (SA-6175) was studied experimentally. In this study, the prepared catalyst was tested in a micro tubular reactor using temperature ranges of 500, 600, 700 and 800 °C at atmospheric pressure, using a total flow rate of 33 ml/min consisting of 3 ml/min of N2, 15 ml/min of CO2 and 15 ml/min of CH4. The calcination was carried out in the range of 500–900 °C. The catalyst is activated inside the reactor at 500–800 °C using hydrogen gas. It was observed that calcination enhances catalyst activity which increases as calcination and reaction temperatures were increased. The highest conversion was obtained at 800 °C reaction temperature by using catalyst calcined at 900 °C and activation at 700 °C. The catalyst characterization conducted supported the observed experimental results. 相似文献
487.
M. H. Annaby A. E. Hamza K. A. Aldwoah 《Journal of Optimization Theory and Applications》2012,154(1):133-153
This paper is devoted for a rigorous investigation of Hahn’s difference operator and the associated calculus. Hahn’s difference operator generalizes both the difference operator and Jackson’s q-difference operator. Unlike these two operators, the calculus associated with Hahn’s difference operator receives no attention. In particular, its right inverse has not been constructed before. We aim to establish a calculus of differences based on Hahn’s difference operator. We construct a right inverse of Hahn’s operator and study some of its properties. This inverse also generalizes both Nörlund sums and the Jackson q-integrals. We also define families of corresponding exponential and trigonometric functions which satisfy first and second order difference equations, respectively. 相似文献
488.
Possible inhibitors preventing human immunodeficiency virus type 1 (HIV-1) entry into the cells are recognized as hopeful next-generation anti-HIV-1 drugs. It is highly desirable to develop a potent inhibitor blocking binding of glycoprotein CD4 of the cell with glycoprotein gp120 of HIV-1, because the gp120-CD4 binding is the initial step of HIV-1 entry into the cells. It has been recently reported that (-)-epigallocatechin gallate (EGCG) from green tea is an inhibitor blocking gp120-CD4 binding. But the inhibitory mechanism remains unknown. For understanding the inhibitory mechanism, extensive molecular docking, molecular dynamics simulations, and binding free-energy calculations have been performed in this study to predict the most favorable structures of CD4-EGCG, gp120-CD4, and gp120-CD4-EGCG binding complexes in water. The results reveal that EGCG binds with CD4 in such a way that the calculated binding affinity of gp120 with the CD4-EGCG complex is negligible. So, the favorable binding of EGCG with CD4 can effectively block gp120-CD4 binding. The calculated CD4-EGCG binding affinity (DeltaG(bind) = -5.5 kcal/mol, K(d) = 94 microM) is in excellent agreement with available experimental data suggesting IC(50) approximately 100 microM for EGCG-blocking CD4-gp120 binding. These results and insights provide a rational basis for future design of novel, more potent inhibitors to block gp120-CD4 binding. 相似文献
489.
We revisit old conjectures of Fermat and Euler regarding the representation of integers by binary quadratic form x 2+5y 2. Making use of Ramanujan’s 1 ψ 1 summation formula, we establish a new Lambert series identity for $\sum_{n,m=-\infty }^{\infty}q^{n^{2}+5m^{2}}We revisit old conjectures of Fermat and Euler regarding the representation of integers by binary quadratic form x
2+5y
2. Making use of Ramanujan’s 1
ψ
1 summation formula, we establish a new Lambert series identity for
?n,m=-¥¥qn2+5m2\sum_{n,m=-\infty }^{\infty}q^{n^{2}+5m^{2}}
. Conjectures of Fermat and Euler are shown to follow easily from this new formula. But we do not stop there. Employing various
formulas found in Ramanujan’s notebooks and using a bit of ingenuity, we obtain a collection of new Lambert series for certain
infinite products associated with quadratic forms such as x
2+6y
2, 2x
2+3y
2, x
2+15y
2, 3x
2+5y
2, x
2+27y
2, x
2+5(y
2+z
2+w
2), 5x
2+y
2+z
2+w
2. In the process, we find many new multiplicative eta-quotients and determine their coefficients. 相似文献
490.
The Ising model with quenched random magnetic fields is examined for single Gaussian, bimodal and double Gaussian random field distributions by introducing an effective field approximation that takes into account the correlations between different spins that emerge when expanding the identities. Random field distribution shape dependence of the phase diagrams, magnetization and internal energy is investigated for a honeycomb lattice with a coordination number q=3. The conditions for the occurrence of reentrant behavior and tricritical points on the system are also discussed in detail. 相似文献